Making a chemical that changes color in different liquids

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Published 2018-09-23
For this video, I decided to make Brooker’s Merocyanine, also called MOED, which exhibits solvatochromism. This means that it its color changes drastically, depending on the solvent that it’s dissolved in. I thought this effect was really cool and I wanted to try it out myself. Also, chemical companies sell it for hundreds of dollars a gram, and I wanted to see how much cheaper I could make it for.

References:
• Procedure: pubs.acs.org/doi/abs/10.1021/ed054p709
• Article Reference: cdn-pubs.acs.org/doi/10.1021/ja971477m

Special thanks to my Patron Jean-Pierre Ribreau (who I forgot to add to the final credit, I'm sorry!!),

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Music in credits (Walker by SORRYSINES): soundcloud.com/sorrysines/walker

All Comments (21)
  • The four five horsemen of chemistry: Ethanol, Dry ethanol, ice cold ethanol, boiling ethanol, distilled water
  • @errr-iw4lz
    This man made Merocyanine to save money but made $1000 diamond sparkling water consistency
  • @sharpblue
    Moral of the video: If you want to solve a problem, add ethanol to it
  • @lmjohnsono
    You're sitting on a gold mine bro. Selling MOED and Red Mercury should make enough to keep this channel going for decades :P
  • @gajbooks
    “Ice Cold Ethanol” would make a great band name.
  • @GonDragon
    Now that you did it, you could upload your thumbnail to the Wikipedia. I'm sure a lot of people would be very pleased of see some HQ picture of this, with the solvents named with tags.
  • @EzmarVoD
    "I still managed to make way more product than I needed, and I also learned something in the end, so this mistake really didn't bother me that much." This is why you are good at what you do.
  • @shadowfire04
    21:07 the moment he said "liquid rocket propellants" I sat up in bed from pure excitement. nilered, don't forget to take care of your glassware, too. we don't want something like the Great Plasma Shattering again...
  • @AIaura
    Holy hell, those self made rocket propellants
  • @tyler89557
    NileRed: Does something Looks back Squirms in slight regret
  • @bluephreakr
    Ahhh, NileRed, my favourite cooking channel.
  • @mowskii5791
    Have you tried making the Vanillin derivative? It should still be solvatochromic but produce different colors.
  • Awesome video, NR! Strictly speaking, the two structures of MOED are resonance forms, not distinct equilibrating minima. Polar solvents cause a polarization of the electron density that makes the charged resonance form more representative of the true structure than the neutral form. As this occurs, the energy gap between the ground and excited states shrinks, causing a shift in color toward red.
  • @ulrichs.3228
    5:13 I can almost hear the roommate from off-screen: "Nile, have you seen my vodka?? I had it in the freezer." -- "Nu-uh."
  • @bene20080
    Why don't you change the foto in Wikipedia with yours? Awesome video
  • @WendigoPsycho
    Idea for edible chem: synthesize calcium sulfate and make tofu.
  • @rutvin8763
    As a lifelong lover of chemistry, this is one of my favorite channels. At every step, I couldn't help but come up with explanations, rationales, or hypotheses for why things happened as they did. Keep up the good work!
  • @dancoulson6579
    16:08 - It makes a beautiful color when you use acetone as the solvent (second in from right).